Wang, Zhuo and Zhang, Pengchao and Li, Junpeng and Zhang, Chong and Jiang, Jia-Xing and Lv, Menglan and Ding, Zhengping and Zhang, Bin (2022) A low-cost naphthaldiimide based organic cathode for rechargeable lithium-ion batteries. Frontiers in Chemistry, 10. ISSN 2296-2646
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Abstract
Recently, the development of cathode materials is becoming an important issue for lithium-ion batteries (LIBs). Compared with inorganic cathodes, the organic cathodes are developing rapidly, ascribing to their distinct merits in light weight, low cost, massive organic resources and high capacity. In this paper, a cost-efficiency naphthaldiimide (NDI) based derivative, 2,7-bis(2-((2-hydroxyethyl) amino) ethyl) benzo[lmn] [3,8] phenanthroline-1,3,6,8(2H, 7H)-tetraone (NDI-NHOH), was used as organic cathode in LIBs. The NDI-NHOH was synthesized easily via one-step process, and it showed very high thermal stability. Through mixing NDI-NHOH with acetylene black and polyvinylidene fluoride (weight ratio of 6:3:1) as composite cathode in lithium-metal based LIBs, the NDI-NHOH presented versatile electrochemical properties. From cyclic voltammetry (CV) test, it exhibited two reversible peaks for oxidation and reduction in the first cycle, respectively. Notably, the oxidation and reduction peaks were located at 2.54, 3.22 and 2.14, 2.32 V vs. Li+/Li, respectively. By employing NDI-NHOH as cathode, it demonstrated a specific capacity of about 80 mAh g−1 in the range of 1.5–3.5 V, where the batteries retained a capacity retention of 50% over 20 cycles. According to the LIBs study, it suggests that the NDI-NHOH-based derivative shows a potentially promising candidate as efficient organic cathode materials for high-performance metal-ions batteries.
Item Type: | Article |
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Subjects: | Eurolib Press > Chemical Science |
Depositing User: | Managing Editor |
Date Deposited: | 21 Jan 2023 05:17 |
Last Modified: | 11 Mar 2024 04:58 |
URI: | http://info.submit4journal.com/id/eprint/1011 |