Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst

Shi, Shunli and Yu, Ying and Zhang, Bingzhen and Zhong, Yicheng and Wang, Lei and Wang, Shuhua and Ding, Shunmin and Chen, Chao (2021) Step by Step Construction of Multifunctional Hollow Double Shell MNPs@MOF as a Powerful Tandem/Cascade Catalyst. Frontiers in Chemistry, 9. ISSN 2296-2646

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Official URL: https://doi.org/10.3389/fchem.2021.738736

Abstract

The development of efficient heterogeneous catalysts for one-pot tandem/cascade synthesis of imines remains meaningful and challenging. Herein, we constructed an Au/MOF catalyst featured hollow and double MOF shell nanostructure. Owing to its structural merits and acid-basic nature, the as-synthesized Void|(Au)ZIF-8|ZIF-8 catalyst exhibited an enhanced synergistically catalytic performance for tandem catalytic synthesis of imines from benzyl alcohol and aniline under air atmosphere and solvent-free condition. Its 170.16 h−1 of turnover frequency (TOF) was 2.5 times higher than that of the reported catalyst with the highest TOF value.

Item Type:	Article
Subjects:	Eurolib Press > Chemical Science
Depositing User:	Managing Editor
Date Deposited:	28 Mar 2023 12:09
Last Modified:	02 Jan 2024 12:54
URI:	http://info.submit4journal.com/id/eprint/815

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